4-tert-Butylcyclohexanol - 4-tert-Butylcyclohexanol

Structural formula
Structural formula of 4-tert-butylcyclohexanol
Structural formula without stereochemistry
General
Name 4-tert-Butylcyclohexanol
other names
  • 4-tert-Butylcyclohexylalkohol
  • Hexahydro-p-tert-butylphenol
  • Patchouli-hexanol
Sum formula C10H20O
Brief description

white solid with characteristic odor [1]

External identifiers / databases
CAS number
  • 98-52-2
  • 937-05-3 (cis)
  • 21862-63-5 (trans)
EC number 202-676-4
ECHA-InfoCard 100.002.434
PubChem 7391
Wikidata Q67195227
characteristics
Molar mass 156.27 g · mol −1
Physical state

fest[1]

density

0,87 g·cm−3[1]

Melting point

62–70 °C[1]

boiling point

224 °C[1]

solubility

practically insoluble in water (<0.1 g · l −1 at 20 ° C) [1]

safety instructions
GHS hazard labeling [1]
07 - Warning

Caution

H and P phrases H: 319
P: 280​‐​305+351+338​‐​337+313​‐​273 [1]
Toxicological data
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

4- tert -Butylcyclohexanol is a chemical compound from the group of alcohols .

Extraction and presentation

4- tert -Butylcyclohexanol can be obtained by reducing 4- tert- butylcyclohexanone (for example with lithium aluminum hydride [2] ) [3] or by hydrogenating 4- tert- butylphenol [4] .

characteristics

4- tert -Butylcyclohexanol is a flammable, hardly inflammable, white solid with a characteristic odor, which is practically insoluble in water. [1]

use

4- tert -Butylcyclohexanol has been used as a fragrance and flavoring substance since the 1960s [4] . [5]

Individual evidence

  1. a b c d e f g h i j k Entry on 4-tert-butylcyclohexanol in the GESTIS substance database of the IFA , accessed on September 8, 2019(JavaScript required) .
  2. ^ NL Allinger, et al .: Organic Chemistry. [Main volume] Walter de Gruyter, 2011, ISBN 978-3-11-082970-9 , pp. 753 ( limited preview in Google Book search).
  3. Francqui Colloquium: A Molecular View of Heterogeneous Catalysis Proceedings of the First Francqui Colloquium, 19-20 February 1996, Brussels. De Boeck Supérieur, 1998, ISBN 978-2-8041-2679-7, S. 154 ( limited preview in Google Book search).
  4. a b D. L. J. Opdyke: Monographs on Fragrance Raw Materials A Collection of Monographs Originally Appearing in Food and Cosmetics Toxicology. Elsevier, 2013, ISBN 978-1-4831-4797-0, S. 156 ( limited preview in Google Book search).
  5. Shmuel Yannai: Dictionary of Food Compounds with CD-ROM. CRC Press, 2012, ISBN 978-1-4200-8352-1, S. 199 ( limited preview in Google Book search).